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Combustion

Combustion researchers rely on laser-based optical diagnostic techniques as essential tools in understanding and improving the combustion process. For example, a majority of researchers use the quantitative data from planar laser-induced fluorescence (PLIF) techniques in order to study various processes, such as internal combustion engines and hypervelocity combustion.

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Laser-Induced Fluorescence in Combustion

In Laser-Induced Fluorescence (LIF), an atom or molecule gets excited by the absorption of a laser photon. When the atom falls back into the ground state after a certain time (typically 1-100nsec), it undergoes radiative emission, known as fluorescence. Since the fluorescence intensity is dependent on parameters such as ground state population, chemical environment, pressure, and temperature, laser-induced fluorescence measurements have become a vital tool in physical chemistry. For example, some applications include the investigation of elementary chemical reactions and trace analytics down to sub-ppm concentrations. In combustion diagnostics, LIF measurements (also called PLIF in planar illumination) are widely utilized. They allow for the qualitative and quantitative detection of flame radicals and combustion intermediates such as OH, C2, CH, CH2O, as well as pollutants like NO and CO.

PLIF Instrumentation

In a simple PLIF setup, a thin sheet of laser (typically a pulsed laser) illuminates a flame or flow field. The resulting fluorescence from the radicals is detected by a gated intensified CCD while the excitation is eliminated using a band pass filter. The spatial, temporal, and intensity information of the fluorescence is useful in engine diagnostics techniques for the measurement of local fuel concentrations and temperature distributions. Although naturally occurring chemical species are often used in PLIF measurements, external tracer particles are also occasionally added to create a fluorescence signal.

PLIF Setup

Simplified PLIF setup

Combustion Research and Princeton Instruments

PI-MAX for PLIF

For over two decades, PI has actively developed solutions for the combustion community, beginning with PI-MAX, the first high-performance, gated ICCD camera. Coupled with spectrograph solutions from Acton Research, PI provides some of the most comprehensive diagnostic tools for combustion.

  • NEW - PI-MAX 3: 1024i camera with near video rate frame rate. Ideal to synchronize with fast repitition rate lasers.
  • World's first ICCD camera with >25% QE in 300nm region and < 9 nsec gating capability for OH-PLIF (PI-MAX:SB)
  • Dual-image capability for PIV applications (CoolSNAP-HQ, PI-MAX 3: 1024i)
  • Integrated, full programmable timing generator (PTG in PI-MAX) and SuperSYNCHRO (in PI-MAX 3) for easy synchronization.
  • Low noise, 16-bit CCD camera for fast kinetics and spectroscopy (PIXIS, PI-MAX, PI-MAX 3: 1024x256)

Recommended Products

PI-MAX/PI-MAX 3

  • Super Blue (SB) intensifier for highest sensitivity in the OH fluorescence region and fast gate times using unique MCP gating technology
  • New Gen III filmless intensifiers with >50% QE and sub-nano second gating capability
  • The latest PI-MAX2 world's first and only 5MHz/16-bit readout speed that keeps up with high repetition rate lasers
  • PI-MAX2: 1003 with high-resolution 1K interline CCD offers dual-image capability
  • All PI-MAX cameras are also suitable for spectroscopy when coupled to spectrometers

CoolSNAP

  • CoolSNAP:HQ allows capture of two high-resolution images 200 nsec apart
  • Short exposure time of ~1 µsec